Progress of Cryogenics and Isotopes Separation , ISSN: 1582-2575
2018, Volume 21, Issue 2
Pages 49-56

LaCoO3 perovskite-type oxide: Synthesis and charcterization towards practical applications

Mirela Dragan 1* , Stanica Enache 1 , Amalia Soare 1 , Konstantin Petrov 1,2 , Mihai Varlam 1

1 National Research and Development Institute for Cryogenics and Isotopic Technologies - ICSI Rm. Valcea, Uzinei Street no. 4, PO Box Râureni 7, 240050, Râmnicu Vâlcea, Romania
2 Academician Evgeni Budevski Institute of Electrochemistry and Energy Systems, Sofia, Bulgaria

*Corresponding author: Mirela Dragan, E-mail: mirela.dragan@icsi.ro and Stanica Enache, E-mail: stanica.enache@icsi.ro, phone: 0250 732744, Fax: 0250 732746

Published: 2018



Abstract

As the physical properties of the final lanthanum cobalt oxide powder material obtained are strongly dependent on the method of preparation, the development of a convenient method for the synthesis of lanthanum cobalt oxide is also essential.
Lanthanum cobalt oxide polycrystalline powder was synthesized through optimized solid-state reaction method, because of advantage given by simplicity and the use of relatively inexpensive oxides as starting materials.
To elucidate the reproducibility of our fabrication technique, the variations in properties among the batch to batch samples were evaluated.
The prepared lanthanum cobalt oxide powder is essentially within a single crystalline phase. The results showed that we realized good reproducibility of batch to batch powder properties, which is one of the most important factors for commercialization.


References

  • Aldebert, J.P. Traverse, 1979
    Mater. Res. Bull.14:303

  • Alvarez, A. Conde-Gallardo, H. Montiel, R. Zamorano, 2016
    About room temperature ferromagnetic behavior in BaTiO3 perovskite
    Journal of Magnetism and Magnetic Materials, 401:196-199

  • Huma Nazli Baig, Jagjeet Kaur Saluja, D. Haranath, 2016
    Investigation of luminescence properties of Dy3+ doped YAlO3 phosphors synthesized through solid state method
    Optik, 127(20):9178-9195

  • J.G. Bednorz and K. A. Müller, 1986
    Possible high T superconductivity in the Ba−La−Cu−O system
    Z. Phys. B. 64(1):189-193

  • I. Djerdj, G. Garnweitner, Su Dangsheng, M.J. Niederberger, 2007
    Solid State Chemistry, 180:2154

  • Dragan Damjanovic, 2001
    Piezoelectric properties of perovskite ferroelectrics: unsolved problems and future research
    Annales de Chimie Science des Matériaux, 26(1):99-106

  • Daniela-Ion Ebrasu, Adnana Zaulet, Stanica Enache, Mirela Dragan, Elena Carcadea, Mihai Varlam, Konstantin Petrov, 2018
    Electrochemical characterization of metal oxide as catalysts oxygen evolution in alkaline media
    Special issue of Bulgarian Chemical Communications, Sofia, Bulgaria, 50(Special Issue A)

  • Stanica Enache, Mirela Dragan, Mihai Varlam, 2017
    Metoda termica directa si eficienta de sinteza a materialelelor perovskite de tip LaCoO3
    CBI nr. A/00470/12.07.2017

  • Stanica Enache, Mirela Dragan, Amalia Soare, Daniela-Ion Ebrasu, Adnana Zaulet, Mihai Varlam, Konstantin Petrov, 2018
    One step solid-state synthesis of lanthanum cobalt oxide perovskites as catalysts for oxygen evolution in alkaline media
    Special issue of Bulgarian Chemical Communications, Sofia, Bulgaria, 50(Special Issue A)

  • Minhua Fang, Xiaolin Yao, Wanwan Li, Yue Li, Miao Shui, Jie Shu, 2018
    The investigation of lithium doping perovskite oxide LiMnO3 as possible LIB anode material
    Ceramics International, 44(7):8223-8231

  • Sudipta Goswami, Dipten Bhattacharya, 2018
    Magnetic transition at ∼150 K in nanoscale BiFeO3
    Journal of Alloys and Compounds, 738:277-282

  • Haas, R.P.W.J. Struis, J.M. J. McBreen, 2004
    Solid State Chemistry, 177:1000

  • D.C. Kim, A.N. Baranov, J.S. Kim, H.R. Kang, B.J. Kim, Y.C. Kim, J.S. Pshirkov, E.V. Antipov, Y.W. Park, 2003
    High pressure synthesis and superconductivity of Ba1−xKxBiO3 (0.35<x<1)
    Physica C: Superconductivity, 383(4):343-353

  • Xiaoyuan Li, Raymond Jeanloz, 1987
    Electrical conductivity of (Mg,Fe)SiO3 perovskite and a perovskite dominated assemblage at lower mantle conditions
    Geophysical Research Letters, 14(11):1075-1078

  • Qing Lin, Xingxing Yang, Jinpei Lin, Zeping Guo, Yun He, 2018
    The structure and magnetic properties of magnesium-substituted LaFeO3 perovskite negative electrode material by citrate sol-gel
    International Journal of Hydrogen Energy, 43(28):12720-12729

  • Thanya Phraewphiphat, Muhammad Iqbal, Kota Suzuki, Yasuaki Matsuda, Masao Yonemura, Masaaki Hirayama, Ryoji Kanno, 2015
    Syntheses, structures, and ionic conductivities of perovskite-structured lithium–strontium–aluminum/ gallium–tantalum-oxides
    Journal of Solid State Chemistry, 225:431-437

  • Sabrina Presto, Pravin Kumar, Salil Varma, Massimo Viviani, Prabhakar Singh, 2018
    Electrical conductivity of NiMo–based double perovskites under SOFC anodic conditions
    International Journal of Hydrogen Energy, 43(9):4528-4533

  • Mirza H. K. Rubel, Akira Miura, Takahiro Takei, Nobuhiro Kumada, M. Mozahar Ali, Masanori Nagao, Satoshi Watauchi, Isao Tanaka, Kengo Oka, Masaki Azuma, Eisuke Magome, Chikako Moriyoshi, Yoshihiro Kuroiwa, and A. K. M. Azharul Islam, 2014
    Superconducting Double Perovskite Bismuth Oxide Prepared by a Low-Temperature Hydrothermal Reaction
    Angewandte Chemie International, 53(14):3599-3603

  • Salles, J.M. Bassat, J. Fouletier, D. Marinha, M.-C. Steil, 2018
    Oxygen pressure dependence of the ionic conductivity of iron-doped calcium titanate
    Solid State Ionics, 324:103-108

  • W.L. Roth, 1964, J. Phys. Chem. Solids, 25:1

  • R.D. Shannon, 1976
    Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
    Acta Crystallographica Section A: Crystal Physics, Diffraction, Theoretical and General Crystallography, 32(5):751-767

  • Thurnaurer, J. Deaderick, 1947, U.S. Patent No. 2,429,588 filed (1941)

  • Patrick Tonui, Saheed O. Oseni, Gaurav Sharma, Qingfenq Yan, Genene Tessema Mola, 2018
    Perovskites photovoltaic solar cells: An overview of current status
    Renewable and Sustainable Energy Reviews, 91:1025-1044

  • Wang Long Wang, Qingjie Meng, Yehui Xue, Xiaole Weng, Pengfei Sun, Zhongbiao Wu, 2018
    Lanthanide perovskite catalysts for oxidation of chloroaromatics: Secondary pollution and modifications
    Journal of Catalysis, 366:213-222

  • Chuangang Yao, Haixia Zhang, Xiaojuan Liu, Junling Meng, Xiong Zhang, Fanzhi Meng, Jian Meng, 2018
    Characterization of layered double perovskite LaBa0.5Sr0.25Ca0.25Co2O5+δ as cathode material for intermediate-temperature solid oxide fuel cells
    Journal of Solid State Chemistry, 265:72-78

  • Parganiha, Yogita & Kaur, Jagjeet & Dubey, Vikas & Shrivastavac, Ravi, 2015
    YAlO3:Ce3+ powders: Synthesis, Characterization, Thermoluminescence and optical studies
    Superlattices and Microstructures, 85:410-417

  • Fenglian Zhang, Xin Zhang, Guoxia Jiang, Na Li, Zhengping Hao, Siqiu Qu, 2018
    H2S selective catalytic oxidation over Ce substituted
    348:831-839

  • Ting Zheng, Jiagang Wu, Dingquan Xiao, Jianguo Zhu, 2018
    Recent development in lead-free perovskite piezoelectric bulk materials
    Progress in Materials Science, 98:552-624

  • Keywords

    perovskite, LaCoO3, oxides powders, solid state reaction, water electrolysis, non-noble metal catalysts


    Tag search perovskite LaCoO3 oxides powders solid state reaction water electrolysis non-noble metal catalysts